Zinc Borohydride

Synthetic Applications of Zinc Borohydride

Manganese borohydride; synthesis and characterization.

Solvent-based synthesis and characterization of α-Mn(BH4)2 and a new nanoporous polymorph of manganese borohydride, γ-Mn(BH4)2, via a new solvate precursor, Mn(BH4)2·1/2S(CH3)2, is presented. Manganese chloride is reacted with lithium borohydride in a toluene/dimethylsulfide mixture at room temperature, which yields halide and solvent-free manganese borohydride after extraction with dimethylsul...

Tetra­methyl­ammonium borohydride from powder data

In the crystal structure of the title compound, C(4)H(12)N(+)·BH(4) (-), the tetra-methyl-ammonium cations are situated on special positions with site symmetry [Formula: see text]m2. The borohydride anions are situated on special positions with 4mm site symmetry and show rotational disorder around the fourfold axis.

Polymer Supported Zinc Borohydride: A Stable, Efficient, Selective, and Regenerable Reducing Agent for Variety of Organic Compounds

The difficult to handle and store zinc borohydride, Zn(BH4)2, is stabilized by supporting it on polyvinylpyridine. This new mild, efficient, selective, and regenerable polymer supported borohydride reducing agent reduces a variety organic compounds such as, aldehydes, a-b-unsaturated carbonyl compounds, acid chlorides, epoxides, disu...

Manganese Borohydride; Synthesis and Characterization Dalton Transactions Paper Manganese Borohydride; Synthesis and Characterization †

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